Changes in redox potential of a nickel-pincer complex bearing reactive secondary thioamide units: Changes caused by deprotonation/protonation reactions on addition of NEt3 and DBU
スポンサーリンク
概要
- 論文の詳細を見る
Shifts of Ni(II)/Ni(III) redox potentials of a nickel-pincer complex, [Ni(SCS)Br] (SCS = 2,6-bis(benzylaminothiocarbonyl)phenyl), on addition of bases have been investigated. The complex showed two-step shifts of the Ni(II)/Ni(III) redox potential, and the shifts are associated to two-step deprotonation of the SCS ligand on addition of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). DBU led to a negative shift of the Ni(II)/Ni(III) redox potential by approximately 500 mV.
論文 | ランダム
- 税務情報開示禁止原則規定に関する再考察--租税条約上の情報交換規定を中心に
- 必要犯則情報の交換に関する考察
- 税法上の訴訟外紛争解決手段に関する一考察
- 潰瘍性大腸炎を合併した原発性硬化性胆管炎の2例(セッション7,III 一般演題,第31回消化器病センター例会,学術情報)
- 重加算税適用をめぐる諸問題 (特集 事例による加算税・重加算税適用と分水嶺)