Liquid crystal electropolymerisation under magnetic field and resultant linear polarised electrochromism
スポンサーリンク
概要
- 論文の詳細を見る
The electrochemical preparation of poly(3,4-ethylenedioxythiophene) (PEDOT) is conducted in liquid crystal (LC) electrolyte solution with nematic (N), cholesteric (Ch*), and smectic A (SmA) phases under a magnetic field. The polymer imprints the molecular arrangement of the LC electrolyte during the polymerisation process. The oriented polymers thus obtained displays optical texture characteristics that resemble those of the LC electrolyte solution. Especially, visualization of SmA domain through PEDOTfibrils is achieved. The magnetic alignment produces linear optical polarisation for the polymers. The PEDOTs thus prepared exhibit good reproducible electroactivity. The present electropolymerisation under magnetic field affords polymer films with linear polarised electrochromism.
- Royal Society of Chemistryの論文
Royal Society of Chemistry | 論文
- Reactions of excited-state benzophenone ketyl radical in a room-temperature ionic liquid
- Ultrathin tough double network hydrogels showing adjustable muscle-like isometric force generation triggered by solvent
- Motion of methanol adsorbed in porous coordination polymer with paramagnetic metal ions
- Hyperbranched 5,6-glucan as reducing sugar ball
- Stereoselective tris-glycosylation to introduce β-(1→3)-branches into gentiotetraose for the concise synthesis of phytoalexin-elicitor heptaglucoside