Radical β-addition to acyclic α-(arylsulfinyl) enones: Pummerer-type rearrangement
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概要
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The reaction of (S,E)-3-(p-tolylsulfinyl)pent-3-en-2-one with an isopropyl radical, generated from isopropyl iodide and triethylborane, gives the non-stereoselective addition product and an unexpected α-(arylsulfanyl) enone which is formed through a radical addition and subsequent Pummerer-type rearrangement. The formation of the α-(arylsulfanyl) enone depends upon the additives used as well as the aryl group on the sulfur.
- Royal Society of Chemistryの論文
- 1998-01-01
Royal Society of Chemistry | 論文
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