Effect of Duty Cycle on Characteristics of CrN
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概要
- 論文の詳細を見る
CrN<inf>x</inf>thin films have been deposited on silicon wafer, 304 stainless steel, and tungsten carbide substrates using pulsed DC reactive magnetron sputtering. A 10 kHz unipolar mode and a N<inf>2</inf>/Ar ratio of 17.5% were used. During the deposition, the substrate was not biased and not heated during the entire deposition time of 30 min. The microstructure, crystalline phase, and mechanical properties of the obtained CrN<inf>x</inf>thin films were examined to investigate the effect of the duty cycle. The results show that the maximum current and power density increase with decreasing duty cycle from 100% (DC) to 5%. Although the thickness of the CrN<inf>x</inf>thin films decreases with decreasing duty cycle, the ratio of the thickness to the pulse on-time shows a maximum of 273.3 nm/min at the lowest duty cycle of 5%. The obtained CrN<inf>x</inf>thin films show a mixture of the Cr<inf>2</inf>N and CrN phases. Moreover, the Cr--N bonding state and the percentages of CrN and Cr<inf>2</inf>N vary with the duty cycle. The effects of the duty cycle on the hardness, coefficient of friction, and corrosion behavior of the CrN<inf>x</inf>thin films are also investigated in this study.
- The Japan Society of Applied Physicsの論文
- 2013-11-25
著者
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Wu Wan-Yu
Department of Materials Science and Engineering, MingDao University, Peetow, Changhua 52345, Taiwan
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Chen Wei-Chih
Surface Engineering Research Center, MingDao University, Peetow, Changhua 52345, Taiwan
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Chen Pin-Hung
Surface Engineering Research Center, MingDao University, Peetow, Changhua 52345, Taiwan
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Chang Chi-Lung
Department of Materials Science and Engineering, MingDao University, Peetow, Changhua 52345, Taiwan
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Ho Chun-Ta
Surface Engineering Research Center, MingDao University, Peetow, Changhua 52345, Taiwan
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Wu Bo-Yi
Department of Materials Science and Engineering, MingDao University, Peetow, Changhua 52345, Taiwan