Various Shapes of ZnO and CdO Nanostructures Grown by Atmospheric-Pressure Chemical Vapor Deposition
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概要
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Various shapes of ZnO and CdO nanostructures were successfully grown on $a$- and $c$-plane sapphire substrates coated with Au nanocolloidal solution by atmospheric-pressure chemical vapor deposition methods under a simultaneous source supply of metal powder (Zn or Cd) and H2O. The ZnO and CdO nanorods (NRs) grown at higher substrate temperatures ($T_{\text{S}}$s) exhibited tapered shapes, resulting from the competition between the axial growth due to the vapor--liquid--solid (VLS) mechanism and the radial growth due to the vapor--solid (VS) mechanism. The alternate source supply of Zn and H2O was found to be effective for suppressing the tapering of ZnO NRs. The appearance of the Y- and T-shaped nanotrees of CdO may be due to the splitting and migration of catalytic particles during the growth process. These results suggest that both the source supply sequence and the substrate temperature are important factors for the shape design of oxide nanostructures.
- 2011-01-25
著者
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Yagi Masakazu
Kagawa National College of Technology, Mitoyo, Kagawa 769-1192, Japan
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Terasako Tomoaki
Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan
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Fujiwara Tetsuro
Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan
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Shirakata Sho
Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan
関連論文
- Various Shapes of ZnO and CdO Nanostructures Grown by Atmospheric-Pressure Chemical Vapor Deposition