Effects of O2- and N2-Plasma Treatments on Copper Surface
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概要
- 論文の詳細を見る
In this work, we investigate the effects of oxygen (O2) and nitrogen (N2) plasma treatments on the copper surface of aluminum/amorphous silicon-nitricarbide/copper (Al/$\alpha$-SiCN/Cu) metal–insulator–metal (MIM) capacitors with respect to their leakage current and breakdown field. It is found that both the O2- and N2-plasma treatments have an adverse effect on the leakage current and breakdown field of MIM capacitors. The MIM capacitors with their Cu surfaces subjected to O2- or N2-plasma treatment exhibit a room-temperature leakage current density several orders of magnitude larger than that of the sample without plasma treatment at the same applied electric field. The room-temperature breakdown fields of the MIM capacitors with O2- and N2-plasma-treated Cu surfaces are 3.8 and 3.2 MV/cm, respectively, while that of the control sample without plasma treatment is 7.8 MV/cm. The increased leakage currents and degraded breakdown fields of the O2- and N2-plasma-treated samples are attributed, respectively, to the presence of metastable Cu–O oxide and Cu–N azide at the Cu surfaces.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2004-11-15
著者
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CHEN Mao-Chieh
Department of Electronics Engineering & The Institute of Electronics, National Chiao Tung University
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JANG Syun-Ming
Department of Dielectric and CMP, Advanced Module Technology Division, Taiwan Semiconductor Manufact
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LIANG Mong-Song
Department of Dielectric and CMP, Advanced Module Technology Division, Taiwan Semiconductor Manufact
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Chiang Chiu-chih
Department Of Electronics Engineering National Chiao-tung University
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Li Lain-jong
Department Of Chemistry National Taiwan University
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Chiang Chiu-Chih
Department of Electronics Engineering, National Chiao-Tung University, 1001 Ta Hsueh Road, Hsinchu 300, Taiwan
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Wu Zhen-Cheng
Department of Dielectric and CMP, Advanced Module Technology Division, Taiwan Semiconductor Manufacturing Company, Science-Based Industrial Park, Hsinchu 300, Taiwan
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Li Lain-Jong
Department of Dielectric and CMP, Advanced Module Technology Division, Taiwan Semiconductor Manufacturing Company, Science-Based Industrial Park, Hsinchu 300, Taiwan
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Liang Mong-Song
Department of Dielectric and CMP, Advanced Module Technology Division, Taiwan Semiconductor Manufacturing Company, Science-Based Industrial Park, Hsinchu 300, Taiwan
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Jang Syun-Ming
Department of Dielectric and CMP, Advanced Module Technology Division, Taiwan Semiconductor Manufacturing Company, Science-Based Industrial Park, Hsinchu 300, Taiwan
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