アパタイト化合物を触媒に用いたバイオマス由来化合物の変換反応：エタノールから１－ブタノール生成
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Calcium phosphate hydroxyapatite, Ca<SUB>10</SUB>(PO<SUB>4</SUB>)<SUB>6</SUB>(OH)<SUB>2</SUB>, is a typical apatite compound which has a high thermal stability and an affinity for organic compounds of biomass derivatives. It has a capacity for substitutions of Ca<SUP>2+</SUP> ions and PO<SUB>4</SUB><SUP>3-</SUP> ions by other cations and anions. Here in, we will report the selective conversions of biomass derivatives, such as ethanol and lactic acid, into useful chemicals over the apatite compounds, such as Ca<SUB>10</SUB>(PO<SUB>4</SUB>)<SUB>6</SUB>(OH)<SUB>2</SUB>, Sr<SUB>10</SUB>(PO<SUB>4</SUB>)<SUB>6</SUB>(OH)<SUB>2</SUB>, Pb<SUB>10</SUB>(PO<SUB>4</SUB>)<SUB>6</SUB>(OH)<SUB>2</SUB>, and Ca<SUB>10</SUB>(VO<SUB>4</SUB>)<SUB>6</SUB>(OH)<SUB>2</SUB>. The apatite compounds were powders prepared by the hydrothermal method. In the ethanol conversion, the Sr-P apatite catalyst exhibited high 1-butanol selectivity (sel. > 80 C-%), which was significantly higher than that over the Ca-P apatite catalyst. In contrast, the Pb-P apatite catalyst selectively gave acetaldehyde, and the Ca-V apatite catalyst accelerated the dehydration into ethylene.
- 公益社団法人 日本表面科学会の論文
公益社団法人 日本表面科学会 | 論文
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