Effect of potassium agents at activated carbon fabricated from rice husks on pore structure and hydrogen storage property

概要

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Activated carbons were fabricated from carbonized rice husks (CRH) by the alkaline activation with KOH and K2CO3. The pore structure and stored hydrogen contents of activated carbons were investigated. The specific surface area of K2CO3 and KOH activated samples were 1177, 1247 m2/g, respectively. The meso-pore volume of K2CO3 activated sample was larger than KOH activated. On the other hands, the micro-pore volume of KOH activated sample was larger than K2CO3 activated. These results indicated that meso-pore was preferentially developed by K2CO3 activation and micro-pore was preferentially developed by KOH activation. The maximum storage hydrogen contents of activated carbon by KOH and K2CO3 were 0.57 and 0.43 wt %, at 298 K and about 10 MPa, respectively. Thus, it suggests that micro-pore influence on stored hydrogen contents is greater than meso-pore. Consequently, for the fabrication of activated carbon which is utilized for hydrogen storage, KOH is an effective activation agent more than K2CO3.
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