Spiro-ammonium Imide Salts as Electrolytes for Lithium Batteries
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概要
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Organic salts based on the bicyclic (spiro) ammonium cation were synthesized with a systematic variation in the size of the rings. The salts show high melting points and plastic crystal phases. The SP-56 salt showed the lowest melting point, highest ionic conductivity, and a reduction potential more positive than that of the Li/Li<SUP>+</SUP> couple; therefore, it was mixed with EC before being employed in a Li/LiFePO<SUB>4</SUB> battery. The battery maintained capacities between 100 and 113 mA h g<SUP>−1</SUP> over 100 cycles.
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
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