Spin-crossover Transition Coupled with Another Solid-Solid Phase Transition for Iron(II) Thiocyanate Complexes Chelated with Alkylated N-(Di-2-pyridylmethylene)anilines
スポンサーリンク
概要
- 論文の詳細を見る
We have prepared spin-crossover [FeL<SUB>2</SUB>(NCS)<SUB>2</SUB>] complexes chelated with alkylated <I>N</I>-(di-2-pyridylmethylene)anilines. The wider irreversible thermal loop across room temperature was observed with the longer alkyl chain introduced (Δ<I>T</I><SUB>C</SUB> = ca. 90 K for a <I>n</I>-C<SUB>16</SUB>H<SUB>33</SUB> derivative). Pressurization prohibits the solid–solid phase transition, leading to the reversible spin crossover.
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
- Spectrophotometric Studies on the Kinetics of Decomposition of Tetramethylmurexide in Acid Medium
- The Crystal Structures of Metal 8-Hydroxyquinolinate. I. Copper 8-Hydroxyquinolinate
- Hydrophile-Lipophile Balance Values for O/W Emulsions Stabilized by Nonionic Surfactants. I. Hydrophile-Lipophile Balance Values of Nonionic Surfactants Determined by Emulsification
- The Formation of Acetylenic Bond by the Elimination Reaction of Some Enol-esters. III. Formation of α, β-Acetylenic Carbonyl Compounds
- Ultraviolet Absorption Spectra of Lead Aldose-cysteinate