Synthesis of Conjugated Rigid-Rod Polyarylenes with (.ETA.4-Cyclobutadiene)cobalt Moieties in the Main Chain.

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• Ni(0)-promoted dehalogenation polycondensation of bifunctional (η<SUP>5</SUP>-cyclopentadienyl)(η<SUP>4</SUP>-cyclobutadiene)cobalt complexes yields rigid-rod π-conjugated polyarylenes, which exhibit the liquid-crystalline behavior both in melts and in solutions.

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公益社団法人 日本化学会 | 論文

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