Rhodium-Catalyzed Carbonylation of 2-Alkynylbenzaldehyde under Water- Gas Shift Reaction Conditions: Formation of Novel Tricyclic Lactones.

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• Rhodium complexes catalyze carbonylation of 2-alkynylbenzaldehyde <B>1</B> under water-gas shift reaction conditions to give novel lactone <B>2</B> as a major product (up to 59% yield), the structure of which is a tricyclic ring system.

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公益社団法人 日本化学会 | 論文

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