ポリヘキシルの合成について (第1報) ポリスチレンのニトロ化に関する研究

概要

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In order to find the more effective method for synthesis of potassium selective resin "polyhexyl", having researched several methods, started from benzaldehyde, acetophenon and polystyrene etc. respectively, we have found that, as material, polystyrene was the most profitable, and decided to synthesize "polyhexyl" from it. In these papers, we inform the nitration of polystyrene as part 1. At first, we found that the polymerisation degree of polystyrene used was about 10<SUP>4</SUP>, and then the best method that produced <I>p</I>-mononitropolystyrene was nitration by nitric acid fuming not heated.
日本海水学会の論文