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Isomerization and hydration of a-longipinene [1] and longicyclene [2] by the action of equimolar mono-, di- or trichloroacetic acids have been studied under anhydrous conditions. Both [1] and [2] yielded isomerization products, longifolene [3] and isolongifolene [4], along with hydration products, longicamphene hydrate [5], longi-R-fenchyl alcohol [6] and longiborneol [7]. Hydration of [1] to give [6] as a major product amounted to 92% of the hydration products under optimum conditions. The compound [7] was the major product (57% at best) in the hydration of [2].
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
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