Co2(CO)8-Catalyzed Ring-Opening Carbonylation of Cyclic Ethers Using N-Silylamines.
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Co2(CO)8-catalyzed ring-opening carbonylation of oxiranes and oxetane smoothly proceeds with high regioselectivity under 1 atm of carbon monoxide at room temperature to give the corresponding β- and γ-siloxy amides in high yields, respectively. [(R3Si)2NR1R2]+[Co(CO)4]− is thought to be an active catalyst species and directs the high regioselectivity of the carbonylation.
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
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