Formation of Self-organizing Structures (Microemulsions, High-internal-phase-ratio-emulsions, and Reverse Vesicles) and their Applications.
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概要
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Surfactants form various self-organizing structures in solution. The relationship between formation of self-organizing structures, especially, microemulsions, high-internal-phase-ratio-emulsions (HIPREs), and reverse vesicles and the phase behavior in water/nonionic surfactant/oil system is reviewed.Ultra-low interfacial tensions and maximum solubilization are attained in microemulsion systems when the HLB (Hydrophile-Lipophile Balance) of surfactant is optimum in a given systems These properties are used for practical applications such as enhanced oil recovery, detergency, etc.The new method to form HIPRE is discussed, In this method, O/W microemulsions are spontaneously changed to HIPRE by changing temperature. Finally, we describe the recent result of reverse vesicles.
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