Tetrakis(pyridine)silver(II) Peroxodisulfate, (Ag(py)4)S2O8, a Reagent for the Oxidative Transformations.
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概要
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Tetrakis(pyridine)silver(II) peroxodisulfate oxidizes aromatic aldehydes to carboxylic acids, benzylic alcohols to carbonyl compounds, aromatic thiols, and allylaryl thioethers to arylsulfonic acids and benzylic carbon–hydrogen bonds to carbonyl groups. α-Hydroxycarboxylic acids and phenylacetic acids are decarboxylated to produce carbonyl compounds. Dibenzyl ether and its sulfur analogue are converted to their corresponding ester and the thioester, respectively.
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
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