Excess Volumes of a Dioxane Isomer+a Non-Polar Liquid System. II. 1,3- or 1,4-Dioxane+Benzene, +2,2,4-Trimethylpentane and +Tetrachloroethene at Several Temperatures II.

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A series of thermodynamic properties for binary mixtures {dioxane isomer+non-polarliquid} have been investigated to clarify the correlation of thermodynamic properties with solution structures of the component molecules.In this report, we measured densities of binary mixtures (dioxane isomer+2, 2, 4-trimethylpentane, or tetrachloroethene, or benzene) at 293.15, 298.15 and 303.15K, and calculated excess volumes and excess thermalexpansion coefficients of these mixtures from the experimental results. 1, 4-dioxane mixtures have the similar volume effects to 1, 3-dioxane mixtures, despite that 1, 4-dioxane is non-polar solvent and 1, 3-dioxane is the Bipolar liquid.The similar discussion has been made from the thermal effects in these mixtures in the previous paper.
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