Role of Defect Structure on Oxygen Ion Conduction.
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概要
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Oxides with brownmillerlite strucutre (A2B2O5) and fluorite structure such as cubic zirconia are known to exhibit high oxygen ion conduction. The oxygen ionic conductivity of these oxides are influenced by defect structure. A role of oxygen vacancy in defect structure is very important factor for the oxygen ion conduction. This report focuses on the relationship between the oxygen ionic conductivity and defect structure. As representative examples, the induction of ionic polarization in brownmillerlite structure, the controlling of order-disorder transition temperature of oxygen vacancy in brownmillerlite related structure and the improvement of ceria (fluorite structure) were introduced from view point of crystallography.
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