Enthalpy of solution of biuret in various aqueous electrolyte solutions and in an urea solution.
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概要
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A calorimeter for enthalpy of solution measurement has been constructed. It is of an isoperibol type, using a quartz thermometer for temperature sensing, and equipped with a special solution mechanism of solid sample. The performance of the calorimeter has been tested by enthalpy of solution of KCl in water at 298.15K. The result was discussed by comparing with literature values.Enthalpies of solution of Biuret in various aqueous electrolyte solutions and in Urea solution were measured at 298.15K, using this calorimeter. The result was discussed in terms of the solute-solute-solvent interactions.
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