Selective epoxidation of chiral 2-methyl-3,4-unsaturated aldehyde acetals.
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概要
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Title compounds were treated with EtAlCl<SUB>2</SUB> or TiC<SUB>3</SUB>OPr<SUP>i</SUP> and <I>t</I>-butyl hydroperoxide (TBHP) at −78 °C, followed by K<SUB>2</SUB>CO<SUB>3</SUB> to give anti-epoxide, which reacted with LiAlH<SUB>4</SUB> at γ-position.
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
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