Stereoselective hydrogenation of unhindered cyclohexanones to axial alcohols with rhodium catalyst.
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概要
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Hydrogenation of unhindered cyclohexanones with rhodium catalyst in isopropyl alcohol or tetrahydrofuran in the presence of hydrochloric acid gives excellent yields of axial alcohols. Steroidal 3,17- and 3,20-diones are selectively hydrogenated at C-3 to give the corresponding 3-axial-hydroxy ketones in high yields.
- 公益社団法人 日本化学会の論文
公益社団法人 日本化学会 | 論文
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