Supramolecular Chemistry: From Host-guest Complexes to Supramolecular Polymers
スポンサーリンク
概要
- 論文の詳細を見る
Combining the concepts of supramolecular chemistry with material science has led to the development of supramolecular polymer chemistry. Although a large number of host-guest motifs have been produced, only a limited number of recognition motifs have been utilized as supramolecular connections within polymeric assemblies. In this account, we describe the molecular recognition of host molecules based on a calix[5]arene and a bisporphyrin, demonstrating unique guest encapsulations; subsequently, these host-guest motifs were applied to the synthesis of supramolecular polymers that display polymer-like properties in both solution and solid states. In addition, we disclose that bisresorcinarenes form supramolecular polymers that are connected via a hydrogen-bonded rim-to-rim dimeric structure, which is composed of two resorcinarene moieties.
- 社団法人 有機合成化学協会の論文
著者
-
Haino Takeharu
Department Of Chemistry Faculty Of Science Hiroshima University
-
Haino Takeharu
Department of Chemistry, Graduate School of Science, Hiroshima University
関連論文
- High Magnetic Field Effects on Biradical Lifetimes : Evaluation of Magnetic Field Dependence and Chain Length Dependence Using Calculated g and Hyperfine Tensors
- Magnetic Field Effects on Intramolecular Exciplex Fluorescence of Chain-Linked Phenanthrene and N,N-Dimethylaniline: Influence of Chain Length, Solvent, and Temperature
- Synthesis of Medium Ring 1,5-Dienes
- Calix[5]arene-Based Receptor for Dumb-Bell-Shaped C_
- Synthesis of a Molecular Container Having an Open Door that Closes on Guest Binding
- P-383 NEW TRITERPENE GALACTOSIDES RELATED TO POUOSIDE FROM A PAPUAN SPONGE, ASTEROPUS SP.
- Structure Elucidation of Briarane Diterpenoids Using Molecular Mechanics Calculations
- Tether-assisted Synthesis of [3]Rotaxane by Olefin Metathesis
- Enantioselective Recognition of Calix[5]arene-based Artificial Receptor Bearing Chiral Macrocycle for Chiral Ethyltrimethylammonium Salts
- Supramolecular Chemistry: From Host-guest Complexes to Supramolecular Polymers