Mass Spectrometric Study on Mechanism of Formation of Organic Molecular Ions.(II)

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概要

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• The total yield curves of the ion formation from several paraffinic and olefinic hydrocarbons were measured and the decomposition processes are discussed.The C3H5+and C2H3+ions from the n-C4H10+ions may be formed by the hydrogen molecule abstraction reaction.The fbrmation of the C2H4+ions from the iso-C4H10+ions and the cis-2-C4H8+ions may be attributed to the hydrogen migration reaction, while the C2H5+ions from the iso-C4H10+ions and the cis-2-C4H8+ions may be formcd by the rearrangement of hydrogen atoms.The relative yield of the ion formation seems to closelycorrelated with each decomposition process.

• 日本質量分析学会の論文

著者

• 大村 一郎

  日立製作所中央研究所

• 大村 一郎

  日立製作所(中央研究所)

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