Determination of the Rate Constants of Homogeneous Reactions in Solution by Using Kinetic Current

概要

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The methods of determination of the rate constants of homogeneous reactions in solution by using kinetic current due to the reaction which foregoes the electrode reaction, are reviewed. The most commonly used basic equations for the kinetic current of the simple first order reaction are interpreted, in respect to the correlations between the equations. The methods of determination of the rate constants are explained with known examples : 1) dissociation and recombination of weak acids, 2) hydration and dehydration of aldehydes and ketones, and 3) formation and opening of the ring forms of aldoses and ketoses. The necessary conditions for the determination of the rate constants by using kinetic current and the common origins for the errors are discussed.
日本ポーラログラフ学会の論文