A.C. Polarographic Determination of the Rate Constant of Electrode Reaction

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概要

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• The relationship between the a.c. polarographic peak height and the rate constant is experimentally investigated on the basis of the theory proposed by Karribara and Matsuda. The a.c. peak height is found to vary with the. reversibility function and a new simple and rapid method evaluating the rate constant k<SUB>s</SUB> of electrode process at standard potential is proposed. For the electrode reaction between zinc in amalgam and zinc ion in 1M sodium hydroxide, the value for k<SUB>s</SUB> was found to be 7.4×10-5 cm/sec.

• 日本ポーラログラフ学会の論文

著者

• 石井 猛

  Department of Chemistry, Ritsumeikan University

• 神原 富民

  Department of Chemistry, Ritsumeikan University

• 神原 富民

  Department of Agricultural Chemistry, Kyoto University

関連論文

• インダクターを用いる交流ポーラログラフ残余電流の抑制〔英文〕
• Application of Laplace-Transformation to Polarography. I. Introduction
• A.C. Polarographic Determination of the Rate Constant of Electrode Reaction

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