Selective ester-exchange reactions of dibenzyl-aspartate and glutamate in the coordination sphere of copper(II) ion.

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概要

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• Copper(II) complexes of the Schiff bases derived from salicylaldehyde and dibenzyl aspartate or glutamate have been prepared for the first time. Upon refluxing the solution of these complexes in methanol for 30 min, bis(α-methyl β-benzyl <I>N</I>-salicylideneaspartato)copper(II) and bis(α-methyl γ-benzyl <I>N</I>-salicylideneglutamato)copper(II) were obtained. The mechanism of these selective ester-exchange reactions in the metal-coordination sphere has been discussed. Several Schiff bases were obtained and characterized.

• 公益社団法人 日本化学会の論文

著者

• Nakao Yasuo

  Chemical Laboratory, Faculty of Education, Okayama University

関連論文

• Selective ester-exchange reactions of dibenzyl-aspartate and glutamate in the coordination sphere of copper(II) ion.

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