A kinetic study of the base hydrolysis of (2-aminoethanol)bis(ethylenediamine)halogenocobalt(III) complexes.

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概要

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• The base hydrolysis of <I>cis</I>-[CoX(etaH)(en)<SUB>2</SUB>]<SUP>2+</SUP>(X=Cl or Br, etaH=2-aminoethanol, en=ethylenediamine) has been studied. The hydrolysis results in the formation of [Co(eta)(en)<SUB>2</SUB>]<SUP>2+</SUP> (≈35%) and [Co(OH)(etaH)(en)<SUB>2</SUB>]<SUP>2+</SUP> (≈65%) at <I>I</I>=1.0 (KNO<SUB>3</SUB>), 25 °C, the product ratio being independent of the pH. The base hydrolysis has also been studied in the presence of sodium azide.

• 公益社団法人 日本化学会の論文

著者

• Ogino Kazuko

  College of Medical Sciences, Tohoku University

関連論文

• A kinetic study of the base hydrolysis of (2-aminoethanol)bis(ethylenediamine)halogenocobalt(III) complexes.

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