Studies on the interaction between mercury(II) chloride and copper(I) halides in solid state.

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概要

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• Kinetics and mechanism of HgCl<SUB>2</SUB>–CuI and HgCl<SUB>2</SUB>–CuBr reactions were studied in solid state. It has been demonstrated that HgCl<SUB>2</SUB> reaches CuI by surface migration and the reaction proceeds through counter diffusion of Cu<SUP>+</SUP> and Hg<SUP>2+</SUP>. Both the reactions follow the parabolic rate law and the activation energies are 77.11±3.84 and 51.08±1.29 kJ/mol. While the former is a complex multi-stage reaction, the latter is a simple exchange process.

• 公益社団法人 日本化学会の論文

著者

• Beg Mirza

  Department of Chemistry, Aligarh Muslim University

• Ahmad Afaq

  Department of Chemistry, Aligarh Muslim University

関連論文

• Studies on the interaction between mercury(II) chloride and copper(I) halides in solid state.
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