Acylthiocyclopropenium ions.
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概要
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On treatment with a mixture of thiocarboxylic acid and perchloric acid in acetic anhydride, cyclopropenone gave acylthiocyclopropenium perchlorate in a good yield. Bis(acylthio)cyclopropene also yielded the salt under similar reaction conditions. The salt was stable under nitrogen at low temperatures, but was easily hydrolyzed to yield the corresponding cyclopropenethione.
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