Thermochemical studies on 3- and 4-nitroanilines and their N,N-dimethyl derivatives.

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概要

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• Standard enthalpies of combustion and of sublimation at 298.15 K were determined and standard enthalpies of formation in crystalline and gaseous states were derived for <I>N</I>,<I>N</I>-dimethyl-3- and <I>N</I>,<I>N</I>-dimethyl-4-nitroanilines by calorimetric measurements. Stabilization energies due to the intramolecular interaction between substituents were evaluated and discussed for these compounds and 3- and 4-nitroanilines.

• 公益社団法人 日本化学会の論文

著者

• Murata Shigeo

  Chemical Thermodynamics Laboratory and Department of Chemistry, Faculty of Science, Osaka University

• Sakiyama Minoru

  Chemical Thermodynamics Laboratory and Department of Chemistry, Faculty of Science, Osaka University

• Furukawa Junichi

  Chemical Thermodynamics Laboratory and Department of Chemistry, Faculty of Science, Osaka University

• Seki Syûzô

  Chemical Thermodynamics Laboratory and Department of Chemistry, Faculty of Science, Osaka University

関連論文

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• Thermochemical studies on 2,4,6-triisopropylbenzophenone and its photo-isomer, 3',5'-diisopropyl-4,4-dimethyl-3-phenyl-1,2-benzocyclobuten-3-ol. Evaluation of magnitude of light energy stored in the latter molecule.
• Thermochemical studies on 3- and 4-nitroanilines and their N,N-dimethyl derivatives.
• Atomization enthalpies of aliphatic compounds with alternately adjacent carbonyl groups and nitrogen atoms.

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