The reaction of 1,1-dimethyl-1-phenacylhydrazinium bromide with aqueous sodium hydroxide.

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概要

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• The reaction of 1,1-dimethyl-1-phenacylhydrazinium bromide with 1 M aqueous sodium hydroxide give benzoic acid, 3-phenyl-1-methylpyrazole, 5-benzoyl-3-phenyl-1-methylpyrazole, and benzonitrile as the major components; the expected product, 2-benzoyl-5-phenylimidazole was formed in only small amounts. Mechanisms to rationalize the formation of the major products are discussed.

• 公益社団法人 日本化学会の論文

著者

• Kano Kunio

  Department Of Psychiatry Kyoto Prefectural University Of Medicine

• Anselme Jean-Pierre

  Department of Chemistry, University of Massachusetts at Boston

• Anselme Jean-Pierre

  Department of Chemistry, University of Massachusetts at Boston, Harbor Campus

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• The reaction of 1,1-dimethyl-1-phenacylhydrazinium bromide with aqueous sodium hydroxide.

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