The reactions of nitrile oxides with methoxy p-benzoquinones.
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概要
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The 1,3-dipolar cycloaddition reactions of nitrile oxides with methoxy <I>p</I>-benzoquinones are discussed in terms of FMO theory. The unusual reaction pattern of methoxy <I>p</I>-benzoquinones with nitrile oxides is interpreted by considering both antibonding secondary orbital interaction and SHOMO(quinone)–LUMO (nitrile oxide) interaction.
著者
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Araki Koji
Institute Of Industrial Science The University Of Tokyo
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Shiraishi Shinsaku
Institute Of Industrial Science The University Of Tokyo
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Araki Koji
Institute of Industrial Science, The University of Tokyo
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Hayakawa Tohru
Institute of Industrial Science, The University of Tokyo
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