Formation process of aluminium nitride by the vapor-phase reaction of aluminium trichloride with ammonia.
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概要
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The reaction products of gaseous AlCl<SUB>3</SUB> with ammonia were AlCl<SUB>3</SUB>·3NH<SUB>3</SUB> at 200–500 °C, AlN, AlCl<SUB>3</SUB>·3NH<SUB>3</SUB>, NH<SUB>4</SUB>Cl at 550–900 °C, and AlN, NH<SUB>4</SUB>Cl at 1000 °C. AlN is considered to be formed by the reaction of gaseous AlCl<SUB>3</SUB>·3NH<SUB>3</SUB>, formed by the reaction of gaseous AlCl<SUB>3</SUB> with ammonia, with ammonia above <I>ca.</I>550 °C.
- 公益社団法人 日本化学会の論文
著者
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Yajima Akimasa
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Park Suh
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Saeki Yuzo
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Akiyama Masayo
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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