Brillouin scattering of supercooled liquids. I. Tri-o-tolyl phosphate.
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概要
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The sound velocities of <I>tri</I>-<I>o</I>-tolyl phosphate in the GHz region were measured by means of the Brillouin scattering method over a wide range of temperatures. In the temperature range from 283 to 313 K, the sound velocity dispersion was observed directly. The relaxation curves of the longitudinal modulus could be analyzed using a B.E.L. model with a parameter of <I>K</I>=0.5. With a rising temperature, a deviation from the B.E.L. model appeared. We considered that the deviation was attributed to the rotational molecular motion of <I>tri</I>-<I>o</I>-tolyl phosphate.
- 公益社団法人 日本化学会の論文
著者
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Koda Shinobu
Department Of Chemical Engineering Nagoya University
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Nomura Hiroyasu
Department Of Chemical Engineering Faculty Of Engineering Nagoya University
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Miyahara Yutaka
Department Of Chemical Engineering Faculty Of Engineering Nagoya University
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Nakamura Masayuki
Department Of Animal Science Faculty Of Agriculture Tohoku University
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