High-spin(5T2)..LAR..RAR..low-spin(1A1) transition in mixed ligand complex (Fe(2,2'-bipyridine)(1,10-phenanthroline)(NCS)2).
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概要
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A new type of the mixed ligand complex [Fe(bpy)(phen)(NCS)<SUB>2</SUB>] (bpy=2,2′-bipyridine and phen=1,10-phenanthroline) has been prepared by two different methods. The influence of the mixed ligand coordination of bpy and phen to a central iron(II) ion is studied by measurements of the temperature variation of magnetic moments and Mössbauer parameters. It has been demonstrated that the mixed coordination tends to make the <SUP>5</SUP>T<SUB>2</SUB>(high-spin) \rightleftharpoons <SUP>1</SUP>A<SUB>1</SUB>(low-spin) transition more gradual. The spin-crossover transition temperature depends on the electronic property as well as the structure of the ligand coordinated to the central iron(II) ion.
- 公益社団法人 日本化学会の論文
著者
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Inoue Hidenari
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Uchida Hiroshi
Department Of Anesthesia Tottori Prefectural Central Hospital
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Takahashi Takeshi
Department Of Agricultural Chemistry The University Of Tokyo
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Nakajima Hiroko
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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Shirai Tsuneo
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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Fluck Ekkehard
Gmelin-Institut der Max-Planck-Gesellschaft
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Fluck Ekkehard
Gmelin Institute for Inorganic Chemistry of the Max Planck Society for the Advancement of Science
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Takahashi Takeshi
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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