The vaporization of the various trace components from aluminoborosilicate glass.
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概要
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The simultaneous vaporization of dopants in aluminoborosilicate glass was investigated by means of mass spectrometry using a Knudsen cell. The detected chemical species were Na, K, Ni, Zn, Rb, Ag, Te, TeO<SUB>2</SUB>, and Cs in the temperature range of 650–800°C. Their vapor pressures were 10<SUP>−6</SUP>–10<SUP>−4</SUP> Pa. The activation energy of vaporization was discussed in relation to the electrostatic force between the vaporizing specie and oxygen. However, lithium, alkali-earth metal elements, alomst all the transition metal elements (such as Fe, Cr, and Ru), and rare-earth metal elements were not detected in the vapor phase, though they were contained in the glass matrix.
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