Hydrates of organic compounds. XIV. The formation of clathrate-like hydrates of tetrabutylammonium amino carboxylates.

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概要

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• The solid–liquid phase diagrams of binary mixtures of water with a series of tetrabutylammonium α-amino carboxylates, (<I>n</I>-C<SUB>4</SUB>H<SUB>9</SUB>)<SUB>4</SUB>NOOCCH(NH<SUB>2</SUB>)R (R=H, CH<SUB>3</SUB>, C<SUB>2</SUB>H<SUB>5</SUB>, <I>n</I>-C<SUB>3</SUB>H<SUB>7</SUB>, and (CH<SUB>3</SUB>)<SUB>2</SUB>CH), were examined. It. It was found that all the salts examined could form hydrates with hydration numbers either around 30 or around 39.

• 公益社団法人 日本化学会の論文

著者

• Usui Hideyuki

  Department of Chemistry, Faculty of Engineering, Yokohama National University

• Nakayama Haruo

  Department of Chemistry, Faculty of Engineering, Yokohama National University

• Matsui Hiroshi

  Radio Isotope Center, Yokohama National University

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• Hydrates of organic compounds. X. The formation of clathrate hydrates of tetrabutylammonium alkanesulfonates.
• Hydrates of organic compounds. XIV. The formation of clathrate-like hydrates of tetrabutylammonium amino carboxylates.
• Hydrates of organic compounds. III. The formation of clathrate-like hydrates of tetrabutylammonium dicarboxylates.

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