The synthesis of CdTe by means of fused salt electrolysis and its characterization.
スポンサーリンク
概要
- 論文の詳細を見る
Crystalline cadmium telluride layers of a cubic structure have been deposited potentiostatically on graphite cathodes by means of fused salt electrolysis employing CdCl<SUB>2</SUB> and TeO<SUB>2</SUB>/Na<SUB>2</SUB>TeO<SUB>3</SUB> in an LiCl–KCl eutectic melt at 450 °C. X-Ray diffraction and scanning-electron-microscope studies show that (i) these layers have a tendency to grow with a preferred orientation along the 〈111〉 direction and (ii) the surface morphology changes drastically with the change in the applied potential. Voltammetric analyses indicate two distinct mechanisms for cadmium telluride deposition; one is the codeposition of cadmium and tellurium occurring at potentials more negative than −0.2 V(vs. Ag/AgCl), and the other is the ionic reaction of the cathodically formed telluride ion with the cadmium ion occurring at potentials more negative than −0.7 V(vs. Ag/AgCl). As-deposited crystals are either n- or p-type, depending on the melt composition and the applied potential.
- 公益社団法人 日本化学会の論文
著者
-
Minoura Hideki
Department Of Applied Chemistry Faculty Of Engineering Gifu University
-
Murayama Minoru
Department Of Dermatology And Occupational Dermatopathology University Of Occupational And Environme
-
SUGIURA Takashi
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University
-
Minoura Hideki
Department of Synthetic Chemistry, Faculty of Engineering, Gifu University
-
Kitakata Masakazu
Department of Synthetic Chemistry, Faculty of Engineering, Gifu University
-
Ueno Yasusada
Department of Synthetic Chemistry, Faculty of Engineering, Gifu University
関連論文
- Pancreatic Diseases : Evaluation with MR Cholangiopancreatography
- Esophageal Cancer Surgery in Elderly Patients 80 Years of Age or Older
- A Unique Case of Squamous Cell Carcinoma Showing Adenocarcinomatous Features with Focal Apocrine Differentiation
- Unusual type of left paraduodenal hernia caused by a separated peritoneal membrane
- スパッタリング法によって作製したSOFC用Ni-イットリア安定化ジルコニアコンポジット薄膜電極
- Effects of Dissolved Cd^2+ and S^2- Ions on the Flatband Potential of CdS Electrode in Aqueous Solution
- Unresectable Advanced Esophageal Cancer Responded to Docetaxel/nedaplatin/5-fluorouracil Therapy: A Case Report
- 電気化学的に誘起された化学析出法における表面吸着種の利用によるCdSナノ微粒子薄膜の作製
- Self Assembled Growth of Nano Particulate Porous ZnO Thin Film Modified by 2,9,16,23-Tetrasulfophthalocyanatozinc(II) by One-Step Electrodeposition
- Reflection of High Power Pulsed Microwave Incident on a Plasma
- Novel Electrochemical Synthesis of CdS Films from Supersaturated Solutions
- Clinical Experience with Smart Care for Respiratory Managementafter Esophageal Cancer Surgery
- Abdominal lymph node metastasis from prostatic adenocarcinoma in a patient with esophageal squamous cell carcinoma
- Fabrication of Lithium-ion Microarray Battery by Electrophoresis
- Esophageal Duplication Cyst with Abscessation: A case report
- The synthesis of CdTe by means of fused salt electrolysis and its characterization.