Synthesis and properties of copper (II) halide complexes with imino oximes.

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概要

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• Two types of imino oxime copper(II) complexes were obtained by the reactions of copper(I) halides CuX (X=Br, I) with imino oximes (3-[2-[(alkylamino)ethyl]imino]-2-butanone oximes or 3-[2-[(dialkylamino)ethyl]imino]-2-butanone oximes, abbreviated as Hdox-enRR′). One type contains the binuclear complexes [Cu<SUB>2</SUB>(dox-enRR′)<SUB>2</SUB>]<SUP>2+</SUP> and uncoordinated halide anions. The magnetic susceptibilities measured over the temperature range 77–320 K show a strong antiferromagnetic spin coupling interaction through the N–O bridge in these complexes. The magnetic behavior can be explained by using the Bleaney–Bowers equation. It is assumed that the complexes of the other type consist of copper(I) and copper(II) in 2:1 ratio without spin-coupling interaction between the copper ions. The plot of the reciprocal magnetic susceptibilities versus temperatures is linear.

• 公益社団法人 日本化学会の論文

著者

• Yamada Shoichiro

  College Of Engineering Osaka City University

• Murahashi Shun-Ichi

  Faculty of Engineering Science and College of General Education, Osaka University

• Murahashi Shun-Ichi

  Faculty of Engineering Science, Osaka University

• Wan Songping

  Faculty of Engineering Science, Osaka University

• Mori Wasuke

  College of General Education, Osaka University

• Wan Songping

  Faculty of Engineering Science and College of General Education, Osaka University

関連論文

• Wire Length Expressions for Analytical Placement Approach
• Synthesis and properties of copper (II) halide complexes with imino oximes.
• Synthesis and properties of copper(II) perchlorate complexes with imino oximes.

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