A Novel and Efficient Method for the Preparation of .ALPHA.-Hydroxyimino Carbonyl Compounds from .ALPHA.,.BETA.-Unsaturated Carbonyl Compounds with Butyl Nitrite and Phenylsilane Catalyzed by a Cobalt(II) Complex.

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概要

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• Various α,β-unsaturated carbonyl compounds, such as α,β-unsaturated esters, α,β-unsaturated ketones, α,β-unsaturated nitriles, and α,β-unsaturated amides, were directly converted to the corresponding a-hydroxyimino carbonyl compounds in high yields on treatment with butyl nitrite and phenylsilane in the presence of a catalytic amount of <I>N</I>,<I>N</I>′-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II) complex under mild conditions.

• 公益社団法人 日本化学会の論文

著者

• MUKAIYAMA Teruaki

  Department of Applied Chemistry, Faculty of Science, Science University of Tokyo

関連論文

• A Novel and Efficient Method for the Preparation of .ALPHA.-Hydroxyimino Carbonyl Compounds from .ALPHA.,.BETA.-Unsaturated Carbonyl Compounds with Butyl Nitrite and Phenylsilane Catalyzed by a Cobalt(II) Complex.

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