Oxidation of trans-1,2-cyclohexanediaminetetraacetatocobaltate(II) by peroxodiphosphate catalyzed by Ag(I) in acetate buffers. A kinetic study.

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概要

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• The kinetics of oxidation of <I>trans</I>-1,2-cyclohexanediaminetetraacetatocobaltate(II) by peroxodiphosphate (PDP) in acetate buffers was studied in the presence of Ag(I). For the first time, this study gives a clear evidence for the involvement of Ag(I)/Ag(II) cycle in the Ag(I)-catalyzed PDP oxidation reactions in acetate buffers. A plausible mechanism consistent with the observed kinetic features is proposed.

• 公益社団法人 日本化学会の論文

著者

• Rao Panuganti

  Physical Chemistry Research Laboratories, School of Chemistry, Andhra University

• Sivaswaroop Pathaneni

  Physical Chemistry Research Laboratories, School of Chemistry, Andhra University

• Anandkumar Kondapi

  Physical Chemistry Research Laboratories, School of Chemistry, Andhra University

関連論文

• Oxidation of trans-1,2-cyclohexanediaminetetraacetatocobaltate(II) by peroxodiphosphate catalyzed by Ag(I) in acetate buffers. A kinetic study.

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