The Mössbauer Effect in Triethyltin Phenyl Derivatives

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概要

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• Substituent effect of triethyltin phenyl derivatives was investigated by means of the <SUP>119</SUP>Sn Mössbauer effect. The isomer shifts obtained for these compounds fall into the range −0.15–−0.18 mm/sec with respect to Pd<SUP>119m</SUP>Sn source. <I>p</I>-Cl and <I>m</I>-Cl derivatives show broadened spectra, which may be ascribed to an unresolved quadrupole splitting. This small quadrupole interaction may be interpreted in terms of the partial ionicity of the bond formed between tin and carbon in phenyl group.

• 公益社団法人 日本化学会の論文

著者

• Watanabe Noriyuki

  Department Of Applied Chemistry School Of Engineering The University Of Tokyo

• Niki Eiji

  Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo

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