Mass Spectrometry of Dyes. IV. Electron Impact Reaction of Nitrophenyl Phenyl Ethers and Their Charge Migration
スポンサーリンク
概要
- 論文の詳細を見る
By the electron impact reaction of substituted 4-nitrodiphenyl ethers (1), the substituents on ring B of (1) cause a reasonable change in the intensity of fragment ions which result from the nitro→ nitrite ester rearrangement. There is a linear correlation of the M<SUP>+</SUP>–NO fragment ion intensity of (1) with the ionization potential of the molecules, and with Hammett σ constants. These evidences suggest that the charge of ring B will be free to migrate to ring A in the ion state, even if they are separated by O-atom.
- 公益社団法人 日本化学会の論文
著者
-
YAMADA Kazutoshi
Department of Materials Science, Faculty of Engineering, Chiba University
-
Konakahara Takeo
Department of Synthetic Chemistry, Faculty of Engineering, Chiba University
-
Konakahara Takeo
Department of Applied Chemistry, Science University of Tokyo
-
Iida Hirotada
Department of Synthetic Chemistry, Faculty of Engineering, Chiba University
-
Iida Hirotada
Department of Industrial Chemistry and Synthetic Chemistry, Faculty of Engineering, Chiba University
-
Yamada Kazutoshi
Department of Chemistry, Tokyo Kyoiku University
-
Yamada Kazutoshi
Department of Synthetic Chemistry, Faculty of Engineering, Chiba University
関連論文
- Computational Analysis of Molecular Recognition in DNA Base-Sequence and Groove by Methidium Chloride Using Molecular Mechanics Calculation
- Conformational Locking by Intramolecular Hydrogen Bonding and Unlocking by Solvation Using 7-Vinylnorcaradienes
- Stereoselective Synthesis of 2-Alkylamino-N-(2'-alkylphenyl)succinimide Conformers
- An MO theoretical study of the photochemical reaction of alkanenitronate anions to form hydroxamic acids.
- Photochemical Reactions of Bridged Polycyclic Ketones
- Kinetic study on the reaction of p-nitrophenyl acetate with 6-substituted 2,4-diamino-1,3,5-triazines.
- Mass Spectrometry of Dyes. IV. Electron Impact Reaction of Nitrophenyl Phenyl Ethers and Their Charge Migration
- Photochemical Reactions of Enamino Ketones
- Sommelet-Hauser rearrangement of oxygen and sulfur containing heteroaromatic sulfonium ylides.
- A convenient method for preparation of 2-(methylthio)alkanoic acids and their related compounds using the carbanions of substituted malonic esters.
- The inclusion effects of cyclodextrins on the photolysis of p-benzoquinone in aqueous solution.
- Photoreduction of aromatic ketones in hexamethylphosphoric triamide(HMPA): Formation of stable coupling products with HMPA.
- Convenient preparation of methylthiomethyl p-tolyl sulfone starting from dimethyl sulfoxide.
- Catalytic activity of PdCl2 complexes having sulfur compounds as ligands.
- Lithio styryl sulfone as an acyl anion synthon.
- The reaction of phenylacetonitriles with benzaldehydes in hexamethylphosphoric triamide solution containing the sodium salt of .ALPHA.,.ALPHA.-dimethylbenzyl hydroperoxide.
- Triisopropoxy Boroxine as a Reducing Agent for Substituted Benzaldehydes
- The photoreaction of pyrazine derivatives.
- Efficient preparation of 3-alkyl(or aryl)thio-1(or 2)-propenyl p-tolyl sulfones.
- A photoreaction of 4-nitrophenylnitromethane in a micellar system.