Formation Constants of Some Bivalent Metal Chelates of <I>N</I>-Phenylbutyrohydroxamic Acid
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概要
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The formation constants for the metal chelates of Mn(II), Ni(II), Zn(II), and Cu(II) with <I>N</I>-phenylbutyrohydroxamic acid have been determined in 50 volume per cent dioxane-water mixture following the Bjerrum-Calvin pH titration technique and maintaining the titration medium at a constant salt background (0.1 M KClO<SUB>4</SUB>) and a temperature 25±0.1°C. The formation constants found are log<I>K</I><SUB>1</SUB>=9.68(Cu), 6.85(Zn), 6.67(Ni), 5.25(Mn), and log<I>K</I><SUB>2</SUB>=8.58(Cu), 5.52(Zn), 5.21(Ni), and 4.09(Mn), the stability order being Mn<Ni<Cu>Zn.
- 公益社団法人 日本化学会の論文
著者
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Shukla J.
Department of Chemistry, Government College of Science
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Tandon S.
Department of Chemistry, Government College of Science
関連論文
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- Formation Constants of Some Bivalent Metal Chelates of N-Phenylbutyrohydroxamic Acid