Schiff Bases Derived from Heptane-2,4,6-trione and Ethylenediamine, and Its Copper(II) and Oxovanadium(IV) Chelates
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概要
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The copper(II) and oxovanadium(IV) complexes of a new Schiff base derived from heptane-2,4,6-trione and ethylenediamine were prepared. Of a macrocyclic two-to-two and an open jaw-shaped two-to-one (trione to diamine) condensation product, only the latter gave mononuclear copper (II) and oxovanadium(IV) complexes. The coordinating sites to the metal ion in each complex are discussed referring to the spectroscopic results.
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