The Crystal Structures of Methylene Dibromide and Methylene Diiodide
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概要
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The crystal structures of methylene dibromide and methylene diiodide (Form II) have been determined by the X-ray diffraction method at about −90°C and about −20°C respectively. Both the crystals are isomorphous, with monoclinic space group <I>C</I><SUB>2<I>h</I></SUB><SUP>6</SUP>–<I>C</I>2/<I>c</I>. Unit cells containing eight molecules have these dimensions: <I>a</I>=12.239(12), <I>b</I>=4.459(15), <I>c</I>=15.212(16) Å, and β=113.54(7)° for methylene dibromide, and <I>a</I>=13.346(3), <I>b</I>=4.720(90), <I>c</I>=16.479(5) Å, and β=114.48(8)° for methylene diiodide. The orientations of the methylene groups have been obtained by lattice-energy calculations.
- 公益社団法人 日本化学会の論文
著者
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Takeuchi Toru
Faculty Of Science Kwansei Gakuin University
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Watanabe Tokunosuke
Faculty Of Science Osaka University
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Watanabe Tokunosuke
Faculty of Science, Kwansei Gakuin University
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Kawaguchi Takemi
Faculty of Science, Kwansei Gakuin University
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Wakabayashi Akira
Faculty of Science, Kwansei Gakuin University
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Matsumoto Mitsuhiro
Faculty of Science, Kwansei Gakuin University
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