Ferricyanide Oxidation of 4-Arylazo-2,6-di-<I>t</I>-butylphenols

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概要

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• Alkaline ferricyanide oxidation of 4-arylazo-2,6-di-<I>t</I>-butylphenols (I) gave molecular nitrogen, diphenyl derivatives (VI), 2,6-di-<I>t</I>-butyl-<I>p</I>-benzoquinone-<I>N</I>-(3′,5′-di-<I>t</I>-butyl-4′-hydroxyphenyl)arylhydrazone (V) and red tarry compounds. Picryl derivative of phenol (I) gave 2,6-di-<I>t</I>-butyl-<I>p</I>-benzoquinone-picrylanil (X) instead of hydrazone (V). The reaction path was studied on the basis of isolated compounds.

• 公益社団法人 日本化学会の論文

著者

• Manda Eiichiro

  National Chemical Laboratory for Industry

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• Ferricyanide Oxidation of 4-Arylazo-2,6-di-t-butylphenols
• The Synthesis and Oxidation of 4-(N-Arylmethylideneamino)-2,6-di-t-butylphenols

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