The Thermodynamic Properties of C<SUB>9</SUB>H<SUB>18</SUB> Naphthenes. I. The Determination of the Equilibrium Constants for the Hydrogenation of Propyl- and Isopropylbenzene and Ethyltoluenes

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概要

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• The equilibria for the hydrogenation of <I>n</I>-propylbenzene, isopropylbenzene, 1-methyl-2-ethylbenzene, 1-methyl-3-ethylbenzene, and 1-methyl-4-ethylbenzene were determined experimentally over the temperature range of 250 to 450°C and under hydrogen pressures ranging from 5 to 50 atm. The data were then used to calculate the values of the free energy and the equilibrium constant of the above reactions and the values of standard free energy of formation from the elements for <I>n</I>-propylcyclohexane, isopropylcyclohexane, 1-methyl-<I>cis</I>-2-ethyl-cyclohexane, 1-methyl-<I>trans</I>-2-ethylcyclohexane, 1-methyl-<I>cis</I>-3-ethylcyclohexane, 1-methyl-<I>trans</I>-3-ethylcyclohexane, 1-methyl-<I>cis</I>-4-ethylcyclohexane, and 1-methyWrawj-<I>trans</I>-ethylcyclohexane.

• 公益社団法人 日本化学会の論文

著者

• Miki Yasuo

  National Chemical Laboratory for Industry

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• The Thermodynamic Properties of C9H18 Naphthenes. I. The Determination of the Equilibrium Constants for the Hydrogenation of Propyl- and Isopropylbenzene and Ethyltoluenes

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