Isomerization of Heptanes over a Palladium–Zeolite Catalyst
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概要
- 論文の詳細を見る
The isomerization of heptane isomers, heptane, 2- and 3-methylhexane, 3-ethylpentane, and 2,3- and 2,4-dimethylpentane, was investigated kinetically over a palladium-zeolite catalyst in the presence of hydrogen at 280–350 °C. First-order rate constants of 11 reaction paths were given with their activation energies and pre-exponential factors. The reaction scheme network including 22 isomerization steps among 9 isomers was constructed through the detailed analysis of primary and secondary reaction products from the individual isomers. Finally, the several proposed isomerization mechanisms were examined on the basis of the present experimental results.
- 公益社団法人 日本化学会の論文
著者
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Sakai Tomoya
Faculty Of Pharmaceutical Sciences Nagoya City University
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Goto Masafumi
Faculty Of Pharmaceutical Science Kumamoto University
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Hatano Kei-ichiro
Faculty of Pharmaceutical Sciences, Nagoya City University
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Kato Manjiro
Faculty of Pharmaceutical Sciences, Nagoya City University
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